Tableau périodique des éléments
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R

Glossary
Radioactivity | Raoult's law | Rare earth elements | Reference electrode | Relative atomic mass | Relative molecular mass

Radioactivity
Radioactivity is the spontaneous emission of radiation and atomic particles from unstable elements. Radioactivity is measured in terms of half-lives and is not affected by physical state or chemical combination.

Raoult's law
Raoult's law is the expression for the vapor pressure pi of component i in an ideal solution

pi = pio xi

where xi is the mole fraction of component i and pio the vapor pressure of the pure substance i.

Rare earth elements
Rare earth elements are the elements Sc, Y, and the lanthanides (La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu).

Reference electrode
Reference electrode is an electrode whose potential is known and against which potentials of other electrodes can be measured. The potential of a reference electrode is completly independent of the analyte concentration.

Table: Potential of a reference electrodes

  Potential vs. SHE, V
  Calomel electrode Ag / AgCl
T, °C 0.1 M 3.5 M Saturate 3.5 M Saturate
15 0.3362 0.254 0.2511 0.212 0.209
20 0.3359 0.252 0.2479 0.208 0.204
25 0.3356 0.250 0.2444 0.205 0.199
30 0.3351 0.248 0.2411 0.201 0.194
35 0.3344 0.246 0.2376 0.197 0.189

Relative atomic mass
The ratio of the average mass per atom of an element to 1/12 of the mass of nuclide 12C. An atomic weight can be defined for a sample of any given isotopic composition. The standard atomic weight refers to a sample of normal terrestrial isotopic composition. The term relative atomic mass is synonymous with atomic weight.

Relative molecular mass
Relative molecular weight of the substance is defined as the sum of relative atomic weights of the elements, multiplied by the number of atoms in the formula of this substance. For example, when calculating the relative molecular weight (Mr) of sulphuric acid (H2SO4)

Mr(H2SO4) = 2×Ar(H) + Ar(S) + 4×Ar(O)
  = 2×1.0079 + 32.066 + 4×15.999
  = 2.0158 + 32.066 + 63.996
  = 98,078


 

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Haut FACULTÉ TECHNOLOGIQUE DE CHIMIE A SPLIT Eni Generalic TABLEAU PÉRIODIQUE DES ÉLÉMENTS version 1.6 Haut
Glossaire des termes de chimie Tableau périodique des éléments Calcul de la masse molaire

Dernière modification: 01.02.2002
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